Till, Marion and Cammarata, Jose and Wolf, Robert and Scott, Daniel J. (2022) Photocatalytic stannylation of white phosphorus. CHEMICAL COMMUNICATIONS, 58 (64). pp. 8986-8989. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P-4) using a cheap, commercially-available distannane, (Bu3Sn)(2), and anthraquinone as a simple photocatalyst. Subsequent 'one pot' transformation of the resulting stannylated monophosphine intermediate (Bu3Sn)(3)P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | P-4 ACTIVATION; RADICALS; ROUTE |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 Feb 2024 09:39 |
| Last Modified: | 07 Feb 2024 09:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/57174 |
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