Poelker, Jennifer and Schaarschmidt, Dieter and Bernauer, Josef and Villa, Matteo and von Wangelin, Axel Jacobi (2022) BIAN-Aluminium-Catalysed Imine Hydrogenation. CHEMCATCHEM, 14 (15): e202200144. ISSN 1867-3880, 1867-3899
Full text not available from this repository. (Request a copy)Abstract
Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride was successfully applied to catalytic hydrogenations of imines. The catalyst [((Dipp)BIAN)Al(mu-H)(2)Li(OEt2)(2)] was easily prepared from the 2e-reduced BIAN derivative and LiAlH4.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC TRANSFER HYDROGENATION; IRON CATALYSTS; REDUCTIVE AMINATION; ZINC-COMPLEXES; NON-INNOCENT; REACTIVITY; METAL; COBALT; CARBAALANES; ZIRCONIUM; aluminium; hydrides; main group metal catalysis; hydrogenation; imines |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Feb 2024 06:34 |
| Last Modified: | 08 Feb 2024 06:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/57344 |
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