Copper(ii)-photocatalyzed decarboxylative oxygenation of carboxylic acids

Reichle, Alexander and Sterzel, Hannes and Kreitmeier, Peter and Fayad, Remi and Castellano, Felix N. and Rehbein, Julia and Reiser, Oliver (2022) Copper(ii)-photocatalyzed decarboxylative oxygenation of carboxylic acids. CHEMICAL COMMUNICATIONS, 58 (28). pp. 4456-4459. ISSN 1359-7345, 1364-548X

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Abstract

Showcasing the concept of light-induced homolysis for the generation of radicals, the Cu-II-photocatalyzed decarboxylative oxygenation of carboxylic acids with molecular oxygen as the terminal oxidant is described. Two Cu-II-carboxylate complexes with different coordination geometries were synthesized and characterized by X-ray analysis, correlating their structure with their ability to initiate light-induced decarboxylations.

Item Type: Article
Uncontrolled Keywords: COPPER(II) CARBOXYLATES
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 08 Feb 2024 06:42
Last Modified: 08 Feb 2024 06:42
URI: https://pred.uni-regensburg.de/id/eprint/57363

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