Vogler, Arnd (2015) Photoluminescence of [Pt(C3Ph3)L-n]PF6 with L = phenylphosphine ligands. Emission from a (Pt-0 to C3Ph3+) MLCT triplet. INORGANIC CHEMISTRY COMMUNICATIONS, 54. pp. 16-18. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The complex cations [Pt-0(C3Ph3)(PPh3)(2)](+) and [Pt-0(C3Ph3)(tripod)](+) with tripod = CH3C(CH2PPh2)(3) contain the smallest Huckel aromat C3R3+ (with n = 0) as ligand. Since this cation is a CT acceptor, the complexes are characterized by low-energy (Pt-0 to C3Ph3+) MLCT states. The complexes show a photoluminescence which originates from the lowest MLCT triplet. (C) 2015 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | EXCITED-STATE PROPERTIES; CYCLOPROPENYL COMPLEX; CRYSTAL; BENZENE; Luminescence; MLCT; Platinum(0); Cyclopropenium ligand; Phenylphosphine ligands |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Jul 2019 12:05 |
| Last Modified: | 23 Jul 2019 12:05 |
| URI: | https://pred.uni-regensburg.de/id/eprint/5738 |
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