Chinchole, Anurag and Henriquez, Marco A. and Cortes-Arriagada, Diego and Cabrera, Alan R. and Reiser, Oliver (2022) Iron(III)-Light-Induced Homolysis: A Dual Photocatalytic Approach for the Hydroacylation of Alkenes Using Acyl Radicals via Direct HAT from Aldehydes. ACS CATALYSIS, 12 (21). pp. 13549-13554. ISSN 2155-5435,
Full text not available from this repository. (Request a copy)Abstract
A dual photocatalytic protocol was developed to generate acyl radicals from readily available aldehydes via hydrogen atom transfer (HAT). Synergistic cooperation, being supported by DFT studies, between earth-abundant iron(III)chloride and 9,10-diphenylanthracene (DPA) to activate the aldehyde for a HAT step proved to be an efficient, economic, and green route for the hydroacylation of electron-deficient alkenes under UV-light irradiation with broad functional group compatibility. This methodology can be conveniently scaled up and applied to produce valuable materials from renewable feedstock chemicals.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CARBOXYLIC-ACIDS; GENERATION; REACTIVITY; PHOTOLYSIS; ACTIVATION; CATALYST; CHLORIDE; iron chloride; HAT; hydroacylation; photocatalysis; acyl radical |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 Feb 2024 13:26 |
| Last Modified: | 06 Feb 2024 13:27 |
| URI: | https://pred.uni-regensburg.de/id/eprint/57387 |
Actions (login required)
 |
View Item |
