Majek, Michal and Filace, Fabiana and Jacobi von Wangelin, Axel (2015) Visible Light Driven Hydro-/Deuterodefunctionalization of Anilines. CHEMISTRY-A EUROPEAN JOURNAL, 21 (12). pp. 4518-4522. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
The defunctionalization of anilines is an important strategy in aromatic-substitution chemistry. Herein, we report on visible light mediated hydro- and deuterodediazonations in solutions of DMF. The mild reaction conditions (DMF, RT, no additives) tolerate various functional groups and allow the site-specific introduction of D atoms to the arene. Mechanistic investigations indicate the participation of photoredox and radical chain pathways and competing abstraction of methyl and formyl hydrogen atoms from DMF.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ARYL DIAZONIUM SALTS; PHOTOREDOX CATALYSIS; REDUCTIVE DEAMINATION; ORGANIC-SYNTHESIS; METAL-FREE; EOSIN Y; DERIVATIVES; AMINES; HYDRODEDIAZONIATION; PROTODEDIAZONIATION; defunctionalization; organocatalysis; photocatalysis; radical reactions |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Jul 2019 14:10 |
| Last Modified: | 22 Jul 2019 14:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/5783 |
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