L-Glutathione-Functionalized Silica Adsorbent for the Removal of Pesticide Malathion from Aqueous Solutions

Vegas-Mendoza, Sonia M. and Gutierrez-Ortega, Jose A. and Moran-Salazar, Rene G. and Cortes-Llamas, Sara A. and Carbajal-Arizaga, Gregorio G. and Peregrina-Lucano, Alejandro A. and Shenderovich, Ilya G. and Torres-Santiago, Gabriela and Gomez-Salazar, Sergio (2022) L-Glutathione-Functionalized Silica Adsorbent for the Removal of Pesticide Malathion from Aqueous Solutions. PROCESSES, 10 (10): 2146. ISSN 2227-9717

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Abstract

An L-glutathione-functionalized silica adsorbent was applied in this study to remove malathion from aqueous media. This adsorbent has demonstrated an improved adsorption efficiency of malathion. The maximum uptake achieved was 130 mg g(-1) at pH 8. Equilibrium was reached after about 90 min. A pseudo-second-order model best described the adsorption kinetics. The adsorption isotherms were best simulated by the Freundlich model. The functional groups are thermally stable up to about 150 degrees C. The elemental analysis results indicated high glutathione ligand densities. The results of this study show that the environmentally friendly L-glutathione functionalized silica is a promising candidate for the removal of malathion from water at the industrial level.

Item Type: Article
Uncontrolled Keywords: ORGANOPHOSPHORUS PESTICIDES; ACTIVATED CARBONS; ADSORPTION; WATER; DEGRADATION; KINETICS; NANOPARTICLES; EQUILIBRIUM; MECHANISMS; ASSAYS; L-glutathione; malathion; wastewater; pesticide removal; adsorption; amino acid; silica
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Central Analytical Services
Depositing User: Dr. Gernot Deinzer
Date Deposited: 20 Feb 2024 07:48
Last Modified: 20 Feb 2024 07:48
URI: https://pred.uni-regensburg.de/id/eprint/58219

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