Reichle, Alexander and Reiser, Oliver (2023) Light-induced homolysis of copper(ii)-complexes - a perspective for photocatalysis. CHEMICAL SCIENCE, 14 (17). pp. 4449-4462. ISSN 2041-6520, 2041-6539
Full text not available from this repository. (Request a copy)Abstract
Over the past decade, photocatalysis has developed into a powerful strategy for the selective functionalization of molecules through radical intermediates. Besides the well-established iridium- or ruthenium-based photocatalysts, which ideally fulfill the requirements for a photocatalyst, such as long excited-state lifetimes and photostability, the shift towards earth-abundant metal-based photocatalysts has so far been less explored. The concept of light-induced homolysis (LIH) for generating radicals has recently gained significant interest as a new platform for inducing photoreactions with earth-abundant 3d-metal complexes despite only having excited-state lifetimes in the low nanosecond range or even below. Cu(ii)-complexes play a prominent role in exploiting this concept, which will be discussed by showcasing recent developments in organic synthesis with a view to identifying the future prospects of this growing field.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CATALYZED CROSS-COUPLINGS; METAL CHARGE-TRANSFER; RADICAL REACTIONS; PHOTOCHEMICAL PROPERTIES; KINETIC CHARACTERISTICS; AROYLOXYL RADICALS; ORGANIC-MOLECULES; CHLORO COMPLEXES; COPPER; CYCLOPROPYLAMINES |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Feb 2024 09:59 |
| Last Modified: | 22 Feb 2024 09:59 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59070 |
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