Kolb, Daniel and Morgenstern, Martin and Koenig, Burkhard (2023) Decarbonylation of benzaldehydes by dual photoorgano-cobalt catalysis. CHEMICAL COMMUNICATIONS, 59 (55). pp. 8592-8595. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
We report a mild alternative to thermally-driven noble-metal catalyzed decarbonylation protocols for the defunctionalization of benzaldehydes in short reaction times. Our cooperative photocatalytic system involves thioxanthone as an inexpensive HAT-agent and a cobalt complex required for selective C(sp(2))-C(sp(2)) bond cleavage. The generated acyl and phenyl intermediates are postulated to be stabilized as cobalt complexes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ESSENTIAL OIL |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2024 05:24 |
| Last Modified: | 28 Feb 2024 05:24 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59110 |
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