Moussa, Mehdi Elsayed and Rummel, Eva-Maria and Eckhardt, Maria and Riesinger, Christoph and Scheer, Manfred (2023) Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals. DALTON TRANSACTIONS, 52 (43). pp. 15656-15659. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The reaction of RC[triple bond, length as m-dash]P (R = Me, tBu, iPr) with Co2(CO)8 and Fe2(CO)9 under mild conditions led to unpredictable fragmentations of the CP triple bond and subsequent formation of clusters with a dimeric Co3E (E = P and RC) and an Fe3P(CR) core, respectively. The reaction of phosphaalkynes RCP (R = tBu, Me, iPr) with an excess of Co2(CO)8 and Fe2(CO)9 leads to unpredictable fragmentations of the CP triple bond with subsequent formation of novel Co and Fe clusters.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; TUNGSTEN; LIGANDS |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2024 05:46 |
| Last Modified: | 28 Feb 2024 05:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59122 |
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