Heinl, Sebastian and Peresypkina, Eugenia and Kremer, Werner and Scheer, Manfred (2023) A lens-shaped supramolecule based on the bulky pentaphosphaferrocene [CpBIGFe(η5-P5)] and CuBr2. CHEMICAL COMMUNICATIONS, 59 (68). pp. 10263-10266. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Besides inherent fullerene-like hollow spheres, the metallasupramolecular chemistry of pentaphosphaferrocenes and CuBr2 afforded a conceptually new product, a compact 3.2 nm sized supramolecule [{1d}(6)(CuBr)(32)(CH3CN)(6)] formed by six largest pentaphosphaferrocene units [(CpFe)-Fe-BIG(& eta;(5)-P-5)] (1d: Cp-BIG = & eta;(5)-C-5(4-nBuC(6)H(4))(5)) so far and a framework of 32 copper and 32 bromide ions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION; C-60; CP-ASTERISK-FE(ETA(5)-P-5); COMPLEXES; MOLECULES; KEPLERATE; CLUSTER; LIGAND; OXIDE; UNITS |
| Subjects: | 500 Science > 540 Chemistry & allied sciences 500 Science > 570 Life sciences |
| Divisions: | Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Mar 2024 05:41 |
| Last Modified: | 01 Mar 2024 05:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59202 |
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