Mandigma, Mark John P. and Kaur, Jaspreet and Barham, Joshua P. P. (2023) Organophotocatalytic Mechanisms: Simplicity or Naivety? Diverting Reactive Pathways by Modifications of Catalyst Structure, Redox States and Substrate Preassemblies. CHEMCATCHEM, 15 (11): e202201542. ISSN 1867-3880, 1867-3899
Full text not available from this repository. (Request a copy)Abstract
Photocatalysis is a powerful tool to assemble diverse chemical scaffolds, yet a bottleneck on its further development is the understanding of the multitude of possible pathways when practitioners rely only on oversimplified thermodynamic and optical factors. Recently, there is a growing number of studies in the field that exploit, inter alia, kinetic parameters and organophotocatalysts that are synthetically more programmable in terms of their redox states and opportunities for aggregation with a target substrate. Non-covalent interactions play a key role that enables access to a new generation of reactivities such as those of open-shell organophotocatalysts. In this review, we discuss how targeted structural and redox modifications influence the organophotocatalytic mechanisms together with their underlying principles. We also highlight the benefits of strategies such as preassembly and static quenching that overcome common reactivity issues (e. g., diffusion rate limits and energetic limits).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRON-TRANSFER PHOTOOXYGENATION; VERSATILE BUILDING-BLOCKS; SINGLET-OXYGEN; PHOTOREDOX CATALYSIS; ORGANIC-DYES; HIGHLY EFFICIENT; EXCITED-STATE; LIGHT; PHOTOOXIDATION; DICYANOANTHRACENE; organophotocatalysis; mechanistic switchover; Marcus theory; anti-Kasha photochemistry; non-covalent assemblies |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Mar 2024 12:27 |
| Last Modified: | 05 Mar 2024 12:27 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59326 |
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