Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis

Rolka, Alessa B. and Archipowa, Nataliya and Kutta, Roger J. and Koenig, Burkhard and Toste, F. Dean (2023) Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis. JOURNAL OF ORGANIC CHEMISTRY, 88 (10). pp. 6509-6522. ISSN 0022-3263, 1520-6904

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Abstract

The syntheses of two novel, organic, and chiral photocatalysts are presented. By combining donor-acceptor cyanoarene-based photocatalysts with a chiral phosphoric acid, bifunctional catalysts have been designed. In preliminary proof-of concept reactions, their use in both enantioselective energy transfer and photoredox catalysis is demonstrated.

Item Type: Article
Uncontrolled Keywords: 2+2 PHOTOCYCLOADDITION REACTIONS; BRONSTED ACID; THIOXANTHONE; ALKYLATION; POTENTIALS; SENSITIZER; ALDEHYDES; RADICALS; IMINIUM; SINGLET;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie > Prof. Dr. Reinhard Sterner
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Physical Chemistry I > Prof. Dr. Patrick Nürnberger
Depositing User: Dr. Gernot Deinzer
Date Deposited: 09 Mar 2024 15:01
Last Modified: 09 Mar 2024 15:01
URI: https://pred.uni-regensburg.de/id/eprint/59415

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