Riesinger, Christoph and Roehner, David and Krossing, Ingo and Scheer, Manfred (2023) Teaching old tricks to new dogs - rational synthesis of multi-decker complexes featuring <i>cyclo</i>-P<sub>5</sub> decks. CHEMICAL COMMUNICATIONS, 59 (30). pp. 4495-4498. ISSN 1359-7345, 1364-548X
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A rational synthetic pathway towards a series of cyclo-P-5-bearing multi-decker complexes was developed. The combination of [Cp*Fe(mu,eta(5 : 5)-P-5)] (A) with low-valent transition metal cations yields a series of triple-decker complexes [Cp*Fe(mu,eta(5 : 5)-P-5)MCp '''][WCA] (M = Cr - Ni; WCA = weakly coordinating anion, Cp ''' = 1,2,4-(Bu3C5H2)-Bu-t). Utilizing the arene complexes [M(C6R6)(2)][WCA](n) (M = Fe, Co) instead allowed the synthesis of the unprecedented cyclo-P-5-containing quadruple-decker complexes [{Cp*Fe(mu,eta(5 : 5)-P-5)}(2)M][pf](n) (M = Fe, Co).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Mar 2024 10:55 |
| Last Modified: | 10 Mar 2024 10:55 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59555 |
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