Shelyganov, Pavel A. and Moussa, Mehdi Elsayed and Seidl, Michael and Zimmermann, Lisa and da Silva, Wagner Menezes and Scheer, Manfred (2023) Novel synthetic route towards heteroleptic pnictogen-rich organometallic-inorganic coordination compounds. DALTON TRANSACTIONS, 52 (48). pp. 18137-18142. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The reaction of the Ag(i) dimer [Ag2(eta 2-A)2(mu,eta 1:eta 1-A)2][TEF]2 (A = [{CpMo(CO)2}2(mu,eta 2-P2)]) possessing labile eta 2-coordinated P2 ligands with the organometallic dipnictogen compounds [{CpMo(CO)2}2(mu,eta 2-EE ')] (E = E ' = As, Sb; E = P, E ' = As, Sb) represents a facile synthetic route towards unprecedented heteroleptic pnictogen-rich supramolecular complexes. This method can also be extended to the analogous Cu(i) dimer and is studied by DFT computations. The reaction of metal dimers stabilised by diphosphorus tetrahedrane [{CpMo(CO)2}2(mu,eta 2-P2)] with the organometallic tetrahedranes [{CpMo(CO)2}2(mu,eta 2-EE ')] (E = P, As, Sb; E ' = As, Sb) allows the synthesis of heteroleptic pnictogen-rich complexes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BUILDING-BLOCKS; BASIS-SETS; COMPLEXES; LIGAND; BEHAVIOR; POLYMERS; DESIGN; ANIONS; CU+; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Mar 2024 10:59 |
| Last Modified: | 10 Mar 2024 10:59 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59558 |
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