Shelyganov, Pavel A. and Moussa, Mehdi Elsayed and Seidl, Michael and Scheer, Manfred (2023) Organometallic–Organic Hybrid Assemblies Featuring the Diantimony Complex [Cp2Mo2(CO)4(μ,η2-Sb2)], AgI Ions and N-Donor Molecules as Building Blocks. CHEMISTRY-A EUROPEAN JOURNAL, 29 (35). ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
The reactions of the organometallic ligand complex [Cp2Mo2(CO)(4)(mu,eta(2)-Sb-2)] (C) with Ag[TEF] ([TEF](-)=[Al{OC(CF3)(3)}(4)](-)) in the presence of a number of di- or polytopic N-donor molecules (1,6,7,12-tetraazaperylene (L1), 2,2'-bipyrimidine (L2), 4,4'-bipyridine (L3), trans-1,2-di(4-pyridyl)ethylene (L4) and 1,3-di(4-pyridyl)propane (L5)), were studied. Depending on the reaction stoichiometry and choice of linker, these reactions lead to the selective formation of dimeric or tetrameric supramolecular coordination complexes as well as 1D and 2D coordination polymers (CPs). The presented compounds are unique examples of supramolecular complexes incorporating both organometallic Sb-donor and organic N-donor molecules as ligands to stabilize metal ions. Moreover, one of the formed compounds, the CP [Ag-4(eta(2 : 1)-C)(4)(L4)(4)](n)[TEF](4n), represents an exceptional 1D polymer incorporating both N- and Sb-donor ligands as connectors for metal ions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION POLYMERS; SILVER(I) COMPLEXES; BIPYRIDYL LINKERS; PI INTERACTIONS; LIGAND COMPLEX; PYRIDINE; DESIGN; PENTAPHOSPHAFERROCENE; ELEMENTS; BEHAVIOR; antimony; N-donor ligands; organometallic-organic hybrid assemblies; silver; supramolecular coordination complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Mar 2024 13:07 |
| Last Modified: | 12 Mar 2024 07:04 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59570 |
Actions (login required)
 |
View Item |
