Grill, Kevin and Dinauer, Sabrina B. and Peresypkina, Eugenia and Virovets, Alexander V. and Scheer, Manfred (2023) Across the Dimensions: A Three-Component Self-Assembly of Pentaphosphaferrocene-based Coordination Polymers. CHEMISTRY-A EUROPEAN JOURNAL, 29 (22). e202203963. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
Pentaphosphaferrocenes [Cp(R)Fe(eta(5)-P-5)] (Cp*=eta(5)-C5Me5) (A), Cp''=eta(5)-C(5)H(3)tBu(2)-1,3 (B)) are excellent building blocks for polymeric assemblies in supramolecular chemistry in combination with coinage metal salts of weakly coordinating anions such as AgSbF6. Adding rigid aromatic dinitriles ortho/meta/para-(NC)(2)C6H4 in a one-pot reaction between [Cp(R)Fe(eta(5)-P-5)] and AgSbF6 leads to various coordination polymers (CPs) by a three-component self-assembly. The sterical demand of the differently substituted cyclopentadiene ligands as well as the rigid constitution of the isomeric dinitriles (NC)(2)C6H4 play a key role in the formation of the isolated CPs. All CPs were characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | FRAMEWORKS; MOLECULE; COMPLEX; LIGAND; METAL; aromatic dinitrile; coordination polymer; metallosupramolecular chemistry; pentaphosphaferrocene; self-assembly |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Mar 2024 10:43 |
| Last Modified: | 13 Mar 2024 10:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59624 |
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