Lehnfeld, Felix and Seidl, Michael and Timoshkin, Alexey Y. and Scheer, Manfred (2023) On the Brink of Decomposition: Controlled Oxidation of a Substituted Arsanylborane as a Way to Labile Group 13-15-16 Compounds. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 26 (27). ISSN 1434-1948, 1099-0682
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The reactivity of the organic-substituted arsanylborane tBuAsHBH(2)NMe(3) (1) towards different elemental chalcogenes as well as organic oxidants such as O-NMe3, Me3Si-O-O-SiMe3, MesCNO and cyclohexenesulfide is reported. By the reaction of 1 with grey selenium, the selenium oxidation product tBuAs(Se)HBH2NMe3 (2) was obtained. For the oxidation with sulfur, the two products tBuAs(S)HBH2NMe3 (3 a) and tBuAs(S)SHBH2NMe3 (3 b) could be isolated as oils. The structural characterization of As(tBuAs(S)SHBH2NMe3)(3) (4) as well as corresponding DFT computations allow insights into the decomposition behavior of 3 a and 3 b in solution. For the reaction of MesCNO with 1, the formation of an unusual As-H activation product Mes-C(NOH)-AstBu-BH2NMe3 (5) is observed. In the reaction with Me3N-O, the first isolatable oxo-arsanylboranes tBuAs(O)HBH2NMe3 (6 a) and tBuAs(O)OHBH2NMe3 (6 b) are obtained, with 6 b also being accessible via the controlled reaction of 1 with air.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | AMINE-BORANE ADDUCTS; METAL-CATALYZED FORMATION; PHOSPHORUS-BORON BONDS; AMMONIA-BORANE; TRANSITION-METAL; INORGANIC POLYMERS; B-N; DEHYDROGENATION; CHEMISTRY; NITROGEN; Arsenic; Boron; Hydroarsination; Main group; Oxidation |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Mar 2024 13:41 |
| Last Modified: | 12 Mar 2024 13:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59772 |
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