Stammler, Michael B. and Bauer, Anton and Alkhurisi, Mohammed H. and Gigl, Ferdinand and Wisser, Florian M. (2024) Micrometre-Sized Porous Polymer Beads as Heterogeneous Molecular Catalysts. CHEMIE INGENIEUR TECHNIK, 96 (3). pp. 309-317. ISSN 0009-286X, 1522-2640
Full text not available from this repository. (Request a copy)Abstract
Porous polymers have great potential as versatile, chemically stable catalyst supports. Yet, shaping of the resulting powders remains a challenge. Here, we demonstrate the use of suspension polymerisation to design micrometre-sized porous polymers beads containing metal binding sites. The good accessibility of the binding sites ensures high catalytic activity, which is demonstrated for two model reactions: photochemical CO2 reduction and transfer hydrogenation of aromatic ketones. Importantly, the shaping of the host material does not affect the catalytic activity of the active site.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COVALENT TRIAZINE FRAMEWORKS; CARBON-DIOXIDE; METAL; REDUCTION; SPECTRA; STATE; IR; Heterogeneous catalysis; Micrometre-sized beads; Porous organic polymer; Rhodium; Suspension polymerisation |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 20 Mar 2024 07:30 |
| Last Modified: | 11 Mar 2025 09:57 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59948 |
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