Canivet, Jerome and Wisser, Florian M. (2023) Metal-Organic Framework Catalysts for Solar Fuels: Light-Driven Conversion of Carbon Dioxide into Formic Acid. ACS APPLIED ENERGY MATERIALS, 6 (18). pp. 9027-9043. ISSN 2574-0962,
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The direct conversion of carbon dioxide into formic acid as renewable feedstock for chemicals or as fuel using sunlight as the sole energy source would provide a crucial step toward a more sustainable industrialized society. While crucial advances have been made using molecular catalyst, their heterogenization within porous framework can provide additional features, resulting in enhanced efficiency. Thanks to their high affinity toward carbon dioxide and high versatility in composition, Metal-Organic Frameworks (MOFs) already offered appealing opportunities for the design of photocatalysts active in the light-driven carbon dioxide reduction into formic acid. In this Spotlight, we look back on a decade of discovery and understanding in the light-driven MOF-catalyzed formic acid production form carbon dioxide leading to a 1000-fold enhancement in productivity and, moreover, open perspectives for the design of novel porous hybrid photoactive platforms.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOCATALYTIC CO2 REDUCTION; VISIBLE-LIGHT; PHOTOCHEMICAL REDUCTION; COORDINATION CHEMISTRY; COMPARING RATES; FORMATE; DERIVATIVES; DESIGN; MOFS; ZR; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Mar 2024 14:26 |
| Last Modified: | 13 Mar 2024 14:26 |
| URI: | https://pred.uni-regensburg.de/id/eprint/59972 |
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