Heinl, Sebastian and Kiefer, Konrad and Balazs, Gabor and Wickleder, Claudia and Scheer, Manfred (2015) The synthesis of the heterocubane cluster [{CpMn}(4)(mu(3)-P)(4)] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds. CHEMICAL COMMUNICATIONS, 51 (70). pp. 13474-13477. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Thermolysis of [CpMn(eta(6)-cht)] with P-4 in 1,3-diisopropylbenzene leads to the formation of the heterocubane [Cp4Mn4P4] (1) in high yields, as a rare example of 'naked' phosphorus containing complexes of manganese. Compound 1 is characterized and studied by DFT calculations and reflection measurements. 1D coordination polymers [{(CpMn)(4)(mu(3)-P)(4)}(CuX)](n) (2-Cl: X = Cl; 2-Br: X = Br) are obtained in the reaction with CuX. Furthermore, it is shown that all four P atoms in 1 can be addressed for a coordination towards cymantrene resulting in [{(CpMn)(4)(mu(3)-P)(4)}{CpMn(CO)(2)}(n)] (3a: n = 1; 3b: n = 2; 3c: n = 3; 3d: n = 4), and shows that 1 is a tetra-topic building block in coordination chemistry.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ORGANIC HYBRID MATERIALS; ONE-DIMENSIONAL POLYMERS; NAKED PHOSPHORUS ATOM; BUILDING-BLOCKS; METAL-COMPLEXES; P-4 ACTIVATION; TRIPLE BOND; PENTAPHOSPHAFERROCENE; CP-ASTERISK-FE(ETA(5)-P-5); LIGANDS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Jul 2019 14:00 |
| Last Modified: | 29 Jul 2019 14:00 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6213 |
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