Gehrtz, P. H. and Hirschbeck, V. and Fleischer, I. (2015) A recyclable CO surrogate in regioselective alkoxycarbonylation of alkenes: indirect use of carbon dioxide. CHEMICAL COMMUNICATIONS, 51 (63). pp. 12574-12577. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Herein, we report a Pd-catalysed alkoxycarbonylation of alkenes based on the use of a recyclable CO2 reduction product, the crystalline and air-stable N-formylsaccharin, as a CO surrogate. The carbonylation proceeds under ambient conditions in an exceptionally complementary regioselective fashion yielding the desired branched products from styrene derivatives and valuable linear esters from alkyl-substituted alkenes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PD-CATALYZED METHOXYCARBONYLATION; N-FORMYLSACCHARIN; ARYL HALIDES; FORMIC-ACID; CARBONYLATION; HYDROFORMYLATION; RUTHENIUM; ETHENE; HYDROESTERIFICATION; FORMALDEHYDE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Ivana Fleischer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 30 Jul 2019 13:44 |
| Last Modified: | 30 Jul 2019 13:44 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6222 |
Actions (login required)
 |
View Item |
