Hossein, Shirdel and Farzin, Marandi and Abbas, Jalilzadeh and Sebastian, Huber and Arno, Pfitzner (2015) Effects of Direction of Bridging of Thiocyanato on the Dimension of Coordination Polymers: Synthesis, Characterization and Single-crystal X-ray Structure Determination of [Cd(4,4 '-dm-2,2 '-bpy)(NCS)(2)](n) and [Cd(4,4 '-dmo-2,2 '-bpy)(NCS)(2)](n) Coordination Polymers. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 34 (7). pp. 1135-1144. ISSN 0254-5861,
Full text not available from this repository. (Request a copy)Abstract
Two new cadmium(II)-thiocyanato coordination polymers with 4,4'-dimethyl-2,2'-bipyridine (4,4'-dm-2,2'-bpy) and 4,4'-dimethoxy-2,2'-bipyridine (4,4'-dmo-2,2'-bpy) as chelating ligands were synthesized and characterized by elemental analysis, IR and H-1 NMR spectroscopy and X-ray crystallography. Thermal properties were also studied as well. These complexes have formed as [Cd(4,4'-dm-2,2'-bpy)(NCS)(2)](n) (1) and [Cd(4,4'-dmo-2,2'-bpy)(NCS)(2)](n) (2). The coordination numbers of Cd-II in 1 and 2 are six (CdN4S2). Direction of bridging of thiocyanato anions in 1 and 2 created one- and two-dimensional coordination polymers, respectively. The supramolecular features in these complexes were guided and controlled by weak directional intermolecular interactions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METAL-ORGANIC FRAMEWORKS; TOPOLOGIES; CONSTRUCTION; 2,2 '-bipyridine; cadmium(II); coordination polymer; weak interactions |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Jul 2019 14:16 |
| Last Modified: | 29 Jul 2019 14:16 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6223 |
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