Heindl, Claudia and Peresypkina, Eugenia V. and Virovets, Alexander V. and Komarov, Vladislav Yu. and Scheer, Manfred (2015) 1,2,4-Triphospholyl anions - versatile building blocks for the formation of 1D, 2D and 3D assemblies. DALTON TRANSACTIONS, 44 (22). pp. 10245-10252. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The potential of K[P3C2R2] (R = Bu-t, Mes) as building blocks in metallo-supramolecular chemistry was investigated and self-assembly processes with Cu(I) halides resulted in the formation of a large variety of unprecedented one-, two- and even three-dimensional aggregates. The 3D networks showed an interesting topological similarity to allotropes of carbon: diamond and the theoretically proposed polybenzene. Furthermore, the negative charge of the phospholyl ligand favoured the generation of cationic CuaXb (a > b, X = Cl, Br, I) assemblies, a challenging area within the well-studied coordination chemistry of CuX units. In addition, the 1D strands were also characterized in solution, revealing the presence of oligomeric units.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION POLYMERS; SUPRAMOLECULAR CHEMISTRY; MOLECULAR-STRUCTURES; SANDWICH COMPLEX; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; CAGE; COPPER(I); UNITS; HEXAPHOSPHAPENTAPRISMANE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 31 Jul 2019 08:34 |
| Last Modified: | 31 Jul 2019 08:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6243 |
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