Franz, Johannes F. and Kraus, Wolfgang B. and Zeitler, Kirsten (2015) No photocatalyst required - versatile, visible light mediated transformations with polyhalomethanes. CHEMICAL COMMUNICATIONS, 51 (39). pp. 8280-8283. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
A visible light mediated, but photocatalyst-free method for the oxidative alpha-CH functionalization of tertiary amines with a broad scope of carbon-and heteroatom nucleophiles using polyhalomethanes has been developed. In addition, the pivotal visible light triggered activation of polyhalomethanes offers mild conditions for efficient Kharasch-type additions onto non-activated olefins. Preliminary mechanistic studies are reported.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BOND-FORMING REACTIONS; DEHYDROGENATIVE COUPLING REACTIONS; PHOTOREDOX CATALYSIS; C-C; TERTIARY-AMINES; DUAL CATALYSIS; OXIDATIVE HYDROXYLATION; MERGING PHOTOREDOX; ARYLBORONIC ACIDS; HIGHLY EFFICIENT; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Kirsten Zeitler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 31 Jul 2019 08:47 |
| Last Modified: | 31 Jul 2019 08:47 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6248 |
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