Hering, T. and Slanina, T. and Hancock, A. and Wille, U. and Koenig, B. (2015) Visible light photooxidation of nitrate: the dawn of a nocturnal radical. CHEMICAL COMMUNICATIONS, 51 (30). pp. 6568-6571. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Highly oxidizing nitrate radicals (NO3 center dot) are easily accessed from readily available nitrate salts by visible light photoredox catalysis using a purely organic dye as the catalyst and oxygen as the terminal oxidant. The interaction of the excited catalyst and nitrate anions was studied by spectroscopic methods to elucidate the mechanism, and the method was applied to the NO3 center dot induced oxidation of alkynes and alcohols.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CERIUM(IV) AMMONIUM-NITRATE; 9-MESITYL-10-METHYLACRIDINIUM CATION; NO3-CENTER-DOT; ACETONITRILE; MECHANISM; OXIDATION; NO3; CYCLIZATIONS; CHEMISTRY; PRODUCTS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 31 Jul 2019 09:21 |
| Last Modified: | 31 Jul 2019 09:21 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6260 |
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