Gieshoff, Tim N. and Villa, Matteo and Welther, Alice and Plois, Markus and Chakraborty, Uttam and Wolf, Robert and Jacobi von Wangelin, Axel (2015) Iron-catalyzed olefin hydrogenation at 1 bar H-2 with a FeCl3-LiAlH4 catalyst. GREEN CHEMISTRY, 17 (3). pp. 1408-1413. ISSN 1463-9262, 1463-9270
Full text not available from this repository. (Request a copy)Abstract
The scope and mechanism of a practical protocol for the iron-catalyzed hydrogenation of alkenes and alkynes at 1 bar H-2 pressure were studied. The catalyst is formed from cheap chemicals (5 mol% FeCl3-LiAlH4, THF). A homogeneous mechanism operates at early stages of the reaction while active nanoparticles form upon ageing of the catalyst solution.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LITHIUM ALUMINUM-HYDRIDE; MULTICOMPONENT COUPLING REACTIONS; SELECTIVE HYDROGENATION; HETEROGENEOUS CATALYSIS; ALKYNE HYDROGENATION; ALKENE HYDROGENATION; GRIGNARD-REAGENTS; REDUCTION; ISOMERIZATION; NANOPARTICLES; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Aug 2019 11:45 |
| Last Modified: | 01 Aug 2019 11:45 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6282 |
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