Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear Cu-I fragments

Fleischmann, Martin and Duetsch, Luis and Moussa, Mehdi Elsayed and Schindler, Andrea and Balazs, Gabor and Lescop, Christophe and Scheer, Manfred (2015) Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear Cu-I fragments. CHEMICAL COMMUNICATIONS, 51 (14). pp. 2893-2895. ISSN 1359-7345, 1364-548X

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Abstract

A simple and straightforward synthesis of a new linear trinuclear Cu-I cluster with polyphosphine ligands is presented. The reaction of this pre-organized Cu-3 precursor with En ligand complexes (E = P, As; n = 2, 5) affords discrete complexes exhibiting end-on eta(1)-coordination of the E-2 ligands or one-dimensional coordination polymers featuring sigma-1,3-bridging E-5 rings, respectively.

Item Type: Article
Uncontrolled Keywords: COMPLEXES; PENTAPHOSPHAFERROCENE; CHAINS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 01 Aug 2019 12:11
Last Modified: 01 Aug 2019 12:11
URI: https://pred.uni-regensburg.de/id/eprint/6297

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