Grassl, C. and Bodensteiner, M. and Zabel, M. and Scheer, M. (2015) Synthesis of arsenic-rich As-n ligand complexes from yellow arsenic. CHEMICAL SCIENCE, 6 (2). pp. 1379-1382. ISSN 2041-6520, 2041-6539
Full text not available from this repository. (Request a copy)Abstract
The reaction of [{eta(5)-Cp''' Co}(2){mu,eta(4:4)-toluene}] with yellow arsenic yields the arsenic-rich As-n ligand complexes [{Cp''' Co(mu,eta(2:2)-As-2)}(2)] (1), [(Cp''' Co)(4)(mu(4),eta(4:4:2:2:1:1)-As-10)] (2) and [(Cp''' Co)(3)(mu(3),eta(4:4:2:1)-As-12)] (3), which were comprehensively characterized. The molecular structure of 1 show a triple-decker complex with two As-2 units forming the middle-deck; compound 2 contains an all-arsenic As-10 analogue of dihydrofulvalene in the molecular structure. The As-12 ligand in 3 represents the largest Asn ligand complex reported so far.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL-COMPLEXES; ELECTRON-DIFFRACTION; CHEMISTRY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Aug 2019 09:37 |
| Last Modified: | 02 Aug 2019 09:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/6320 |
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