Elsayed Moussa, Mehdi and Bauer, Susanne and Grassl, Christian and Riesinger, Christoph and Balazs, Gabor and Scheer, Manfred (2024) Synthesis and Characterization of Novel Cobalt Carbonyl Phosphorus and Arsenic Clusters. MOLECULES, 29 (9): 2025. ISSN , 1420-3049
Full text not available from this repository. (Request a copy)Abstract
Phosphorus- and arsenic-containing cobalt clusters are an interesting class of compounds that continue to provide new structures with captivating bonding patterns. Although the first members of this family were reported 45 years ago, the number of such species is still limited within the broad family of transition metal complexes bearing pnictogen atoms. Herein, we present the reaction of Co2(CO)8 as a cobalt source with a number of phosphorus- and arsenic-containing compounds under variable reaction conditions. These reactions result in various known and novel cobalt phosphorus and cobalt arsenic clusters in which different nuclearity ratios between P/As and Co exist. All those clusters were characterized by X-ray structural analysis and partly by IR, 31P{1H} NMR, EI-MS and elemental analysis. This comprehensive study is the first detailed study in this field that reveals the richness of compounds that could be obtained only by modifying the ratio of used reactants and the involved reaction conditions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | X-RAY CRYSTAL; COMPLEXES; ANALOG; phosphorus; arsenic; cobalt clusters; carbonyl; interstitial |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 Jul 2025 08:15 |
| Last Modified: | 17 Jul 2025 08:15 |
| URI: | https://pred.uni-regensburg.de/id/eprint/63546 |
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