Parzefall, Maria and Peresypkina, Eugenia and Rummel, Eva-Maria and Moussa, Mehdi Elsayed and Scheer, Manfred (2024) One-dimensional Polymers derived from a Sterically Demanding 1,3-Diphosphete Complex. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 650 (5-6). ISSN 0044-2313, 1521-3749
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The 1,3-disphosphete complex [CpBnCo(eta 4-P2C2tBu2)] (1) is prepared from the reaction of the sterically demanding [CpBnCo]n (CpBn=C5(CH2C6H5)5) with tert-butyl phosphaalkyne (tBu-C equivalent to P). The reaction of 1 with copper halides CuX (X=Cl, Br, I) leads to the formation of one-dimensional coordination polymers of the general formula [{(CpBnCo)(mu 3,eta 4 : 1 : 1-(PCtBu)2)}{Cu(mu-X)}2(MeCN)]n (X=Cl (2), Br (3), I (4)). All compounds are studied in solution by multinuclear NMR spectroscopy and mass spectrometry and in the solid state, by single crystal X-ray diffraction and 31P{1H} MAS NMR. +image
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CHEMISTRY; 1,3-diphosphete; coordination polymer; copper; cobalt; phosphaalkynes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 18 Jul 2025 06:07 |
| Last Modified: | 18 Jul 2025 06:07 |
| URI: | https://pred.uni-regensburg.de/id/eprint/63563 |
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