Bronsted acid-catalyzed hydroarylation of activated olefins

Fleischer, Ivana and Pospech, Jola (2015) Bronsted acid-catalyzed hydroarylation of activated olefins. RSC ADVANCES, 5 (1). pp. 493-496. ISSN 2046-2069,

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Abstract

A mild, regiospecific Bronsted acid-catalyzed hydroarylation of activated olefins, capable of the formation of quinone methide-like intermediates, has been investigated. Variously substituted 2- and 4-vinylphenols, 4-vinylaniline or 6-vinyl-naphthalen-2-ol were successfully implemented in a sequential protonation and Friedel-Crafts-type alkylation reaction of electron-rich arenes.

Item Type: Article
Uncontrolled Keywords: O-QUINONE METHIDES; C-H ACTIVATION; INTERMOLECULAR HYDROARYLATION; UNACTIVATED OLEFINS; BENZYLIC ALCOHOLS; IN-SITU; STYRENES; ALKYLATION; INDOLES; ARENES;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Ivana Fleischer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 05 Aug 2019 07:34
Last Modified: 05 Aug 2019 07:34
URI: https://pred.uni-regensburg.de/id/eprint/6381

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