Supramolecular compounds assembled from the heteroleptic tetrahedral complex [{CpMo(CO)2}2(μ,η<SUP>2</SUP>-AsSb)] and metal salts

Moussa, Mehdi Elsayed and Shelyganov, Pavel A. and Seidl, Michael and Zimmermann, Lisa and Scheer, Manfred (2024) Supramolecular compounds assembled from the heteroleptic tetrahedral complex [{CpMo(CO)2}2(μ,η<SUP>2</SUP>-AsSb)] and metal salts. CHEMICAL COMMUNICATIONS, 60 (35). pp. 4703-4706. ISSN 1359-7345, 1364-548X

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Abstract

The reaction of the tetrahedral complex [{CpMo(CO)(2)}(2)(mu,eta(2)-AsSb)] with Cu-I and Ag-I salts is presented which gives unprecedented neutral and cationic supramolecular aggregates featuring mixed As/Sb-donor molecules as ligands/linkers between metal ions.

Item Type: Article
Uncontrolled Keywords: DER-WAALS RADII; WHITE PHOSPHORUS; P-4 ACTIVATION; BASIS-SETS; LIGAND; MOLECULES; POLYMERS; ANTIMONY; DESIGN; BONDS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 29 Jul 2025 08:22
Last Modified: 29 Jul 2025 08:22
URI: https://pred.uni-regensburg.de/id/eprint/64073

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