Dinauer, Sabrina B. and Szlosek, Robert and Piesch, Martin and Balazs, Gabor and Reichl, Stephan and Prock, Lukas and Riesinger, Christoph and Walter, Marc D. and Scheer, Manfred (2024) Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η<SUP>5</SUP>-E5)] (E = P, As) - unprecedented structural motifs of the resulting polypnictogen ligands. DALTON TRANSACTIONS, 53 (24). pp. 10201-10207. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
A general synthetic procedure to neutral homo- and heterobimetallic cage compounds exhibiting various structural motifs of the polypnictogen ligands starting from [Cp*Fe(eta(5)-E-5)] (E = P (1), As (2); Cp* = C5Me5) is reported. The impact of the implemented transition metal precursors {Cp ''' M} (M = Cr, Mn, Fe, Ni; Cp ''' = 1,2,4-tBu(3)C(5)H(2)) emphasises the variability of the isolated complexes exhibiting a broad variety of structural motifs of the pnictogen ligands. Spectroscopic, crystallographic, and theoretical investigations provide insight into the structure of the partially unprecedented polypnictogen ligands.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Sep 2025 11:12 |
| Last Modified: | 10 Sep 2025 11:12 |
| URI: | https://pred.uni-regensburg.de/id/eprint/64097 |
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