Hauer, Sebastian and Reitz, Justus and Koike, Taichi and Hansmann, Max M. and Wolf, Robert (2024) Cycloadditions of Diazoalkenes with P4 and tBuCP: Access to Diazaphospholes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 63 (38). ISSN 1521-3773
Full text not available from this repository. (Request a copy)Abstract
Diazoalkenes readily react with tert-butylphosphaalkyne (tBuCP) and white phosphorus (P-4) to afford novel phosphorus heterocycles, 3H-1,2,4-diazamonophospholes and 1,2,3,4-diazadiphospholes. Both species represent rare examples of neutral heterophospholes. The mechanism of formation and the electronic structures of these formal (3+2) cycloaddition products were analyzed computationally. The new phospholes form structurally diverse coordination compounds with transition metal and main group elements. Given the growing number of stable diazoalkenes, this work offers a straightforward route to neutral aza(di-)phospholes as a new ligand class.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 5-MEMBERED PHOSPHORUS-HETEROCYCLES; BOND COVALENT RADII; WHITE PHOSPHORUS; ACTIVATION; ELEMENTS; FUNCTIONALIZATION; COMPLEXES; Diazoalkenes; main-group chemistry; azaphospholes; transition-metal chemistry; nitrogen heterocycles |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 16 Dec 2025 08:17 |
| Last Modified: | 16 Dec 2025 08:17 |
| URI: | https://pred.uni-regensburg.de/id/eprint/64114 |
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