Stanic, Petra and Smokrovic, Kristina and Maltar-Strmecki, Nadica and Herak, Mirta and Meurer, Florian and Bodensteiner, Michael and Hennig, Christoph and Molcanov, Kresimir (2024) Structural Variety of Extended Arrays of Pancake-Bonded TCNQ Radicals: Steric Effect of the Bulky Cations. CRYSTAL GROWTH & DESIGN, 24 (22). pp. 9365-9378. ISSN 1528-7483, 1528-7505
Full text not available from this repository. (Request a copy)Abstract
Six novel salts of the TCNQ radical anion with various sterically bulky cations, involving polycyclic, nonaromatic, and acyclic cations, were prepared and studied. The influence of sterically bulky cations on packing efficiency is studied, and it is shown that the formation of pancake bonding between TCNQ radicals is not hindered. Different arrays of stacked TCNQ, ranging from 0D (isolated radicals) to 1D (infinite chains) to 2D are described, and their magnetic properties have been studied.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | FIELD-INDUCED GAP; HYDROGEN-BOND; PI-STACKING; SPIN; SALTS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Central Analytical Services |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Oct 2025 10:39 |
| Last Modified: | 28 Oct 2025 10:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/64738 |
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