Nan, Hailing and Cheng, Beiyi and Zhang, Duo and Wang, Kaiping and Wang, Shuli and Xu, Bingxin and Zhang, Shuwei and Koenig, Burkhard and Zhang, Guodong (2024) Direct Diazoarylation of [1.1.1]Propellane with Arenediazonium Salts: A Modular Assembly of Arylated Diazo Bicyclo[1.1.1]pentanes. ORGANIC LETTERS, 26 (39). pp. 8424-8429. ISSN 1523-7060, 1523-7052
Full text not available from this repository. (Request a copy)Abstract
A mild and concise diazoarylation of [1.1.1]propellane is described, which provides a modular approach to arylated diazo bicyclopentanes (BCPs). This reaction proceeds smoothly under basic conditions without requiring other additives or catalysts. The substrate scope shows that various electron-withdrawing and electron-donating groups are tolerated, and the subsequent modifications provide a novel avenue for assembling arylamino-BCP analogs.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ROUTE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 18 Nov 2025 09:36 |
| Last Modified: | 18 Nov 2025 09:36 |
| URI: | https://pred.uni-regensburg.de/id/eprint/64769 |
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