Haberstroh, Jan and Taube, Clemens and Fidelius, Jannis and Schulz, Stephen and Israel, Noel and Dmitrieva, Evgenia and Gomila, Rosa M. and Frontera, Antonio and Wolf, Robert and Schwedtmann, Kai and Weigand, Jan J. (2024) A neutral diphosphene radical: synthesis, electronic structure and white phosphorus activation. CHEMICAL COMMUNICATIONS, 60 (65). ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
(ClImDipp)P-P(Dipp)(center dot) (1(center dot)), a rare example of a neutral, mixed substituted diphosphene radical, has been prepared by reduction of (ClImDipp)PP(Dipp)[OTf] (2[OTf]) and (ClImDipp)PP(Cl)(Dipp) (3) with cobaltocene (CoCp2) (ClImDipp = 4,5-dichloro-1,3-bis(1,3-diisopropylphenyl)-imidazol-2-yl, Dipp = 2,6-diisopropylphenyl). Radical compound 1(center dot) readily activates white phosphorus (P4), resulting in the formation of an intriguing octaphosphane butterfly compound P8(ClImDipp)2(Dipp)2 (4). The mixed-substituted diphosphene radical has been isolated and characterised. Upon reaction with white phosphorus, the compound forms an octaphosphane.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Nov 2025 10:00 |
| Last Modified: | 05 Nov 2025 10:00 |
| URI: | https://pred.uni-regensburg.de/id/eprint/65020 |
Actions (login required)
 |
View Item |
