Meyer, Andreas Uwe and Slanina, Tomas and Heckel, Alexander and Koenig, Burkhard (2017) Lanthanide Ions Coupled with Photoinduced Electron Transfer Generate Strong Reduction Potentials from Visible Light. CHEMISTRY-A EUROPEAN JOURNAL, 23 (33). pp. 7900-7904. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
Metal ions can have beneficial effects on photoinduced electron transfer. Merging such metal-ion-coupled electron transfer (MCET) with consecutive photoinduced electron transfer (conPET) enables the one-electron reduction of chlorobenzene with blue light in the presence of diisopropylethylamine as an electron donor. The presence of the metal ions extends the substrate scope of the photoredox catalysis to extreme reduction potentials (beyond - 3 V vs. SCE).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ORGANIC-SYNTHESIS; SAMARIUM DIIODIDE; PHOTOREDOX CATALYSIS; ARYL HALIDES; CARBONYL-COMPOUNDS; ALKYL-HALIDES; FLAVIN ANALOG; EOSIN Y; IODIDE; COMPLEXES; aryl radical; C-C bond formation; lanthanides; photoredox catalysis; photoreduction |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:10 |
| Last Modified: | 11 Feb 2019 13:18 |
| URI: | https://pred.uni-regensburg.de/id/eprint/700 |
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