Organocatalytic synthesis of axially chiral atropisomers

Renzi, P. (2017) Organocatalytic synthesis of axially chiral atropisomers. ORGANIC & BIOMOLECULAR CHEMISTRY, 15 (21). pp. 4506-4516. ISSN 1477-0520, 1477-0539

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Abstract

This Review summarises the recent progress made in the organocatalytic synthesis of atropisomeric compounds. Methodologies based on dynamic kinetic resolution and direct access to BINOL-like biaryls are described. A particular emphasis is given to reaction mechanisms and to the development of strategies to obtain stable products by increasing the barrier to atropisomer interconversion during the reaction.

Item Type: Article
Uncontrolled Keywords: DYNAMIC KINETIC RESOLUTION; ENANTIOSELECTIVE SYNTHESIS; ATROPOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; BIARYL COMPOUNDS; BROMINATION; ARYLATION; ACIDS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Depositing User: Petra Gürster
Date Deposited: 14 Dec 2018 13:10
Last Modified: 01 Oct 2020 07:38
URI: https://pred.uni-regensburg.de/id/eprint/709

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