Highly Efficient Organic Light-Emitting Diode Using A Low Refractive Index Electron Transport Layer

Salehi, Amin and Ho, Szuheng and Chen, Ying and Peng, Cheng and Yersin, Hartmut and So, Franky (2017) Highly Efficient Organic Light-Emitting Diode Using A Low Refractive Index Electron Transport Layer. ADVANCED OPTICAL MATERIALS, 5 (11): 1700197. ISSN 2195-1071,

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Abstract

A low refractive index electron transport layer (ETL) can be very effective in enhancing the out-coupling efficiency of an organic light-emitting diode (OLED). However, most organic films show a refractive index close to 1.8. In this work, it has been discovered that tris-[3-(3-pyridyl) mesityl] borane (3TPYMB) has a low refractive index of 1.65 (at 550 nm), which is the lowest refractive index ETL among the commonly used ETLs up to date. Using 3TPYMB as an ETL, a solution processed OLED is demonstrated with nearly a 76% enhancement in external quantum efficiency (EQE). Optical simulation results of this study show that 59% of the enhancement comes from the low refractive index 3TPYMB, and the remaining 17% from the change in charge balance due to the 3TPYMB ETL in the OLED devices.

Item Type: Article
Uncontrolled Keywords: OPERATIONAL STABILITY; HOST MATERIALS; SKY-BLUE; DEVICES; OLEDS; GREEN; FLUORESCENCE; RED; electron transport layers; low refractive indexes; organic light emitting diodes; thermally activated delayed florescence
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Dec 2018 13:10
Last Modified: 11 Feb 2019 13:28
URI: https://pred.uni-regensburg.de/id/eprint/718

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