Vogler, Arnd (2017) Photoredox reactions of binuclear iron(II) and (III) disulfide complexes. Disulfide as CT acceptor and donor. INORGANIC CHEMISTRY COMMUNICATIONS, 80. pp. 33-35. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
In analogy to peroxide, disulfide is an oxidant as well as a reductant. Accordingly, as a ligand of a reducing metal center, low-energy MLCT transitions can occur, while with oxidizing metals low-energy LMCT transitions should be observed. Such MLCT and LMCT excitations are expected to induce redox reactions. The complexes [CpFe(II)(CO)(2)](2)mu-S-2 (Cp=C5H5) and {[Fe(III)(CN)(5)](2)mu-S-2}(6-) are suitable examples to explore this behavior. (C) 2017 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRONIC-STRUCTURE; SULFUR PROTEINS; PHOTOCHEMISTRY; CLUSTERS; SPECTRA; Iron complexes; Disulfide complexes; Photoredox reactions; MLCT; LMCT |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:10 |
| Last Modified: | 15 Feb 2019 11:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/732 |
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