Development and Application of a Recyclable High-Load Magnetic Co/C Hybrid ROMP-Derived Benzenesulfonyl Chloride Reagent and Utility of Corresponding Analogues

Faisal, Saqib and Zang, Qin and Maity, Pradip K. and Brandhofer, Agnes and Kearney, Patrick C. and Reiser, Oliver and Grass, Robert N. and Stoianova, Diana and Hanson, Paul R. (2017) Development and Application of a Recyclable High-Load Magnetic Co/C Hybrid ROMP-Derived Benzenesulfonyl Chloride Reagent and Utility of Corresponding Analogues. ORGANIC LETTERS, 19 (9). pp. 2274-2277. ISSN 1523-7060, 1523-7052

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Abstract

The development and application of high-load, recyclable magnetic Co/C hybrid ROMP-derived benzenesulfonyl chloride and analogues is reported. The regeneration and utility of these reagents in the methylation/alkylation of various carboxylic acids is demonstrated via efficient retrieval of the magnetic reagent with a neodymium magnet. Additional reactions employing the analogue sulfonic acid and in situ generated magnetic benzenesulfonyl azide are also reported.

Item Type: Article
Uncontrolled Keywords: CARBOXYLIC-ACIDS; METATHESIS POLYMERIZATION; ALKYLATING REAGENTS; DIAZODICARBONYL COMPOUNDS; CONTINUOUS-FLOW; ONE-POT; EFFICIENT; ESTERIFICATION; CATALYSTS; NANOPARTICLES;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Dec 2018 13:10
Last Modified: 20 Feb 2019 07:03
URI: https://pred.uni-regensburg.de/id/eprint/892

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