Electrolytes for lithium and lithium ion batteries: From synthesis of novel lithium borates and ionic liquids to development of novel measurement methods

Amereller, M. and Schedlbauer, T. and Moosbauer, D. and Schreiner, C. and Stock, C. and Wudy, F. and Zugmann, S. and Hammer, H. and Maurer, A. and Gschwind, R. M. and Wiemhoefer, H. -D. and Winter, M. and Gores, H. J. (2014) Electrolytes for lithium and lithium ion batteries: From synthesis of novel lithium borates and ionic liquids to development of novel measurement methods. PROGRESS IN SOLID STATE CHEMISTRY, 42 (4). pp. 39-56. ISSN 0079-6786

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Abstract

This review covers various aspects of electrolyte investigations. The first section reports on synthesis and characterization of lithium salts and ionic liquids, including some unpublished recent work. The next part is devoted to transference number measurements of lithium ions. It contains recently published work and new results on this rarely investigated but important topic. Studies of anodic aluminum dissolution with our novel fast impedance scanning electrochemical quartz microbalance (FIS-EQCM) follow next. After a short introduction to the method, some recently published results are reviewed along with some yet unpublished material. We have also shown that the solubility of solids and gases in liquids can be measured with this equipment, including the solubility of lithium salts in ionic liquids. First results of FIS-EQCM studies show that electroplating and corrosion of lithium and subsequent dissolution of the SEI can be studied as well. The last parts of this manuscript are dedicated to the investigation of miscellaneous topics that are of interest for studies of electrolytes for LIBs. (C) 2014 Elsevier Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: TRANSFERENCE NUMBER MEASUREMENTS; DOUBLE-LAYER CAPACITORS; ELECTROCHEMICAL CHARACTERIZATION; PROPYLENE CARBONATE; CURRENT COLLECTOR; CONCENTRATION-DEPENDENCE; NONAQUEOUS ELECTROLYTES; TEMPERATURE-DEPENDENCE; LIPF3(CF2CF3)(3) LIFAP; TRANSPORT-PROPERTIES; Lithium borates; Lithium ion cells; Fast impedance scanning electrochemical quartz microbalance; Lithium ion transference numbers; Aluminium corrosion; Lithium anodes
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Heiner Jakob Gores
Depositing User: Petra Gürster
Date Deposited: 13 Aug 2020 13:36
Last Modified: 13 Aug 2020 13:36
URI: https://pred.uni-regensburg.de/id/eprint/9098

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