Heinl, S. and Scheer, M. (2014) Low temperature activation of S-8, Se-red and alpha-Te with [(CpFe)-Fe-BIG(CO)(2)] radicals. DALTON TRANSACTIONS, 43 (43). pp. 16139-16142. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The bulky dimeric iron complex, [(CpFe)-Fe-BIG(CO)(2)](2), readily activates elemental chalcogens (S-8, Se-red and alpha-Te) under mild conditions at room temperature. Six compounds containing Q(2)(2-) ligands (Q = S. Se) and a Te2- ligand, respectively, were isolated and completely characterized, including by X-ray diffraction techniques.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURE; BRIDGING LIGANDS; COMPLEXES; SULFUR; REACTIVITY; CHEMISTRY; CLUSTER; CORE; IRON; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Aug 2019 07:18 |
| Last Modified: | 08 Aug 2019 07:18 |
| URI: | https://pred.uni-regensburg.de/id/eprint/9193 |
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