Peresypkina, Eugenia V. and Heindl, Claudia and Schindler, Andrea and Bodensteiner, Michael and Virovets, Alexander V. and Scheer, Manfred (2014) Crystal structure of a giant supramolecule encapsulating o-carborane. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 229 (11). pp. 735-740. ISSN 2194-4946, 2196-7105
Full text not available from this repository. (Request a copy)Abstract
A giant quasi-spherical supramolecule [{Cp*Fe(eta(5)-P-5)}(12)(CuBr)(18.8)] encapsulating o-carborane was prepared by the reaction between CuBr and [Cp*Fe(eta(5)-P-5)] (Cp* = pentamethylcyclopentadienyl) and structurally characterized. The crystal structure can be treated as solid solution of various [(Cp*Fe(eta(5)-P-5))(12)(CuBr)(n)] supramolecules with n = 18-20. Two crystals obtained from different syntheses differ in the location of vacant CuBr positions and solvent molecules. Surprisingly, the supramolecules are packed following the low-density reo (ReO3) packing.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PENTAPHOSPHAFERROCENE; MOLECULES; CHEMISTRY; CLUSTERS; disorder; encapsulation; pentaphosphaferrocene; pseudomerohedral twinning; supramolecule |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Aug 2019 14:31 |
| Last Modified: | 08 Aug 2019 14:31 |
| URI: | https://pred.uni-regensburg.de/id/eprint/9261 |
Actions (login required)
 |
View Item |
