Heindl, Claudia and Heinl, Sebastian and Luedeker, David and Brunklaus, Gunther and Kremer, Werner and Scheer, Manfred (2014) Novel polymeric aggregates of pentaphosphaferrocenes and monocationic coinage metal salts - Synthesis of [{Cp*Fe (eta(5)-P-5)}{Cu(GaCl4)}(2)](n) and [{(CpFe)-Fe-BIG(eta(5)-P-5)}Ag](n) [Al(OC(CF3)(3))(4)](n). INORGANICA CHIMICA ACTA, 422. pp. 218-223. ISSN 0020-1693, 1873-3255
Full text not available from this repository. (Request a copy)Abstract
The reaction of pentaphosphaferrocenes [(CpFe)-Fe-R(eta(5)-P-5)] (CPR = Cp* = eta(5)-C5Me5, Cp-BIG = eta(5)-C-5(4-(BuC6H4)-Bu-n)) with monocationic salts of copper and silver leads to the formation of [{Cp*Fe(eta(5)-P-5)}{Cu(GaCl4)}(2)](n) (2) and [{(CpFe)-Fe-BIG(n(5)-P-5)}Ag](n) [Al{OC(CF3)(3)}(4)](n). (3), respectively, representing the rare structural motifs of a 1,2,3,4- or a 1,3 coordination mode of the cyclo- P5 unit. Both the 2D network as well as the 1D polymer are obtained from self-assembly processes and characterized by X-ray structure analysis. Compound 2 exemplifies a sheet-like structure, whose layers are linked by short Cl...H-contacts, whereas the structure of 3 is comprised of cationic strands, whose positive charge is balanced by the weakly coordinating anion [Al{OC(CF3)(3)}(4)]. Dissociative properties of both polymeric complexes are compared by solution and solid state NMR spectroscopy. (C) 2014 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION CHEMISTRY; SILVER(I) CATIONS; LIGAND COMPLEXES; PHOSPHORUS; COPPER; MOLECULES; Coordination chemistry; Pentapho sphaferrocene; Coinage metal salt; Weakly coordinating anion; CPBIG |
| Subjects: | 500 Science > 540 Chemistry & allied sciences 500 Science > 570 Life sciences |
| Divisions: | Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Aug 2019 13:33 |
| Last Modified: | 12 Aug 2019 13:33 |
| URI: | https://pred.uni-regensburg.de/id/eprint/9442 |
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