Nano-droplet formation in water/ethanol or isopropanol/mosquito repellent formulations

Marcus, Julien and Mueller, Martina and Nistler, Joseph and Touraud, Didier and Kunz, Werner (2014) Nano-droplet formation in water/ethanol or isopropanol/mosquito repellent formulations. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 458. pp. 3-9. ISSN 0927-7757, 1873-4359

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Abstract

It was recently demonstrated that nano-structures were present in water/ethanol/oil systems, where theoil was either octanol or fragrance molecules. The goal of the present work is to check if such structuresexist also in other, related systems and if a general concept can be deduced from these observations. To this purpose, natural and synthetic mosquito repellent molecules were investigated, which represent nearly all repellents used on the market. For the ternary water/alcohol (ethanol or isopropanol)/repellent systems ternary phase diagrams were established. The presence and the ordering of the nano-droplets were checked and characterized with dynamic and static light scattering and conductivity measurements. Based on these results it can be concluded that a nano-ordering with generally an organic continuum exists in hydro-alcoholic commercial mosquito repellents, and thus that these systems are not simply molecular solutions. This might have a consequence for diffusion processes in the skin. (C) 2013 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: MICROEMULSIONS; Mosquito repellents; Nano-droplet; Dynamic light scattering; Static light scattering; Conductivity measurements
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry)
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Depositing User: Dr. Gernot Deinzer
Date Deposited: 19 Dec 2019 12:19
Last Modified: 19 Dec 2019 12:19
URI: https://pred.uni-regensburg.de/id/eprint/9536

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