Vogler, Arnd and Shenderovich, Ilya G. (2014) Photochemistry of deprotonated rhenium(I) (3,3 '-dihydroxy-2,2 '-bipyridine) tricarbonyl chloride. Photoisomerization at the chelate in basic solution. INORGANICA CHIMICA ACTA, 421. pp. 496-499. ISSN 0020-1693, 1873-3255
Full text not available from this repository. (Request a copy)Abstract
In basic solution the complex Re(I) [bipy(OH)(2)] (CO)(3)Cl with bipy(OH)(2) = 3,3'-dihydroxy-2,2'-bipyridine is deprotonated at one of the phenolic OH substituents. Upon irradiation of the anion {Re[bipy(OH)(O)](CO)(3)Cl}(-) the yellow solution becomes reddish brown. It is suggested that the photolysis is associated with an isomerization at the chelate from N,N to N,O coordination. (C) 2014 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | NMR CHEMICAL-SHIFTS; OPTICAL-PROPERTIES; METAL COMPLEXES; HYDROGEN-BONDS; WATER; LIGAND; 8-HYDROXYQUINOLINE; EQUILIBRIUM; GEOMETRIES; CHEMISTRY; Photochemistry; Isomerization; Rhenium complexes; Polypyridines |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Aug 2019 09:23 |
| Last Modified: | 28 Aug 2019 09:23 |
| URI: | https://pred.uni-regensburg.de/id/eprint/9667 |
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