Photocatalytic disassembly of tertiary amine-based dendrimers to monomers and their application to the 'catch and release' of a dye in aqueous solution

Sharma, Anindra and Koenig, Burkhard and Jayaraman, Narayanaswamy (2014) Photocatalytic disassembly of tertiary amine-based dendrimers to monomers and their application to the 'catch and release' of a dye in aqueous solution. NEW JOURNAL OF CHEMISTRY, 38 (8). pp. 3358-3361. ISSN 1144-0546, 1369-9261

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Abstract

Photocatalytic disassembly of tertiary amine-based poly(propyl ether imine) dendrimers, in the presence of either 9,10-anthraquinone or riboflavin tetraacetate and O-2(g), leads to di- and tripropanolamine monomers. An application is shown by solubilisation of a water-insoluble dye, Sudan I, in aq. dendrimer solution ('catch'), followed by its 'release' upon disassembly of the dendrimer.

Item Type: Article
Uncontrolled Keywords: PHOTOINDUCED ELECTRON-TRANSFER; DENDRITIC POLYMERS; RIBOFLAVIN; DEGRADATION; DERIVATIVES; WATER;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 12 Sep 2019 07:17
Last Modified: 12 Sep 2019 07:17
URI: https://pred.uni-regensburg.de/id/eprint/9841

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